The preparations of molybdenum oxide film include vapor deposition, electrochemistry deposition, sputtering, sol-gel and other ways.
Vapor Deposition
Advantages: simple equipment, easy to operate.
Defects:
1) Film and substrate bonding strength is insecure, easy to peel;
2) Expensive equipment, complex technology, and not easy to produce large area and uniform oxide film.
Electrochemistry Deposition
Advantages:
1) Easy to prepare large area film;
2) The composition of film can be controlled by controlling the composition of potential (or electric current) and solution;
3) The thickness and surface morphology of the film can be controlled by controlling the electricity using depositing;
4) Simple and safe. It doesn’t need high vacuum, high temperature and dangerous gas.
Defects:
1) The film has loose structure and contains much moisture;
2) The growth and growth speed of the crystal nucleus on the substrate surface can not be controlled, the crystal structure is irregular, and is generally polycrystalline.
Sputtering Method
Advantages:
1) The substrate temperature is low;
2) The prepared films have good crystallinity, and epitaxial single crystal films can be obtained;
3) The film has good properties.
Defects: The growth rate of sputtering is slow, and the composition of the film has a certain deviation from the target.
Sol-gel
Advantages:
1) The composition and doping of the film can be controlled accurately;
2) Easy to prepare large area film, and suitable for mass production, simple equipment, low cost;
3) Compatible with integrated process, suitable for fabricating ferroelectric integrated devices.
Defects:
1) The compactness of the film is poor, and the crazing phenomenon is easy to occur;
2) The process parameters are difficult to master.
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